The anaerobic zone is first in the process because it requires an environment free of Dissolved Oxygen (D.O.) and available molecularly combined oxygen such as nitrite and nitrate. A mixture of plant influent and Return Activated Sludge (RAS), which becomes Mixed Liquor Suspended Solids (MLSS), flows into the head of the zone. The RAS contains microorganisms (bugs), some of which are Phosphorus Accumulating Organisms (PAO’s) that are starved of Volatile Fatty Acids (VFA’s). The Influent is full of VFA’s, so the PAO’s go on a feeding frenzy. When they start consuming the VFA’s, they require oxygen to stay active. However, there is none available, so they strip the oxygen from Phosphate, which causes phosphorus to go into solution. The PAO’s have now released their phosphorus reserve and will want to reobtain it later in the treatment process.
The first anoxic basin is designed to remove nitrate from the water in an environment free of D.O. The Influence water does not contain any nitrates, but it contains ammonia (NH3) and Ammonium (NH4+). The ammonium is converted into nitrates in the aeration basins and recycled from there to the first anoxic. With the first anoxic getting fed the BOD that passed through the anaerobic basin, the bugs start to consume all the new “food.” While the bugs are active, they need oxygen to maintain their activity; however, there is no D.O. in the basin, consuming the oxygen attached to the nitrate molecule. After the oxygen is removed from nitrate, nitrogen gas is released into the atmosphere, known as Denitrification.
The aeration basin is where the cleaning of the water begins, and the removal of ammonium occurs. Ammonium is removed because it is toxic to aquatic life. The water is cleaned to achieve a Turbidity of less than 2.0 NTU to reach GVW’s A+ Water Effluent requirements. The MLSS going over the first anoxic basin into the aeration basin weir now contains BOD, bugs that require oxygen, phosphorus, ammonia, ammonium, and little to no nitrate. Green Valley Water uses high-efficiency turbo blowers to provide air to the basin and maintain a D.O. of 1.75mg/L to 2.5mg/L, depending on the season. Nitrifying bacteria cause a biochemical reaction that converts ammonium and oxygen into nitrite and water. The nitrite is converted into nitrate. The creation of nitrate causes potential effluent issues, so the MLSS must be returned to the first anoxic basin to remove them safely. Ammonia and ammonium always maintain a ratio that is temperature and pH-dependent. With the ammonium turning into nitrite, the ammonia converts to ammonium. Thus, entirely getting rid of all ammonium/ammonia known as Nitrification.
Nitrifying bacteria are slow growers, so in order to grow and maintain them, GVW operates the ASP at a Sludge Retention Time (SRT). If the SRT is too old, the PAO’s will not perform their jobs effectively because they will lose the battle to Glycogen Accumulating Organisms (GAO’s), which will cause too much Phosphorus in the effluent. An old SRT can also cause turbidity to rise. If the SRT is too young, the nitrifying bacteria will not thrive, potentially hampering the ability to treat the water to Class A+ standards. The BOD, both settable and non-settable, is consumed by all the other bacteria. The bacteria are consumed by the more prominent (typically older) bugs. These more giant bugs form flocs and settle, leaving behind clear water. The SRT determines which type of larger and smaller bugs are in the ASP.
With there being readily available oxygen in the aeration basin, luxury Phosphorus uptake happens with the PAO’s. The PAO’s were starving for Phosphorus after releasing it in the anaerobic basin. Since they have entered a “starvation” mode, they will take back the Phosphorus they released and extra Phosphorus that came in with the Plant Influent. The PAO’s settle as part of the flocculent in the clarifiers. The Phosphorus gets removed in the Waste Activated Sludge (WAS).
The second anoxic basin is a “polishing” zone. Its environment contains no D.O. other than that which comes over the weir from the nitrification basin. Additionally, the second anoxic basin removes what little bit of nitrate remains.
The MLSS goes from the reaeration basin to the clarifiers. Any nitrate left in the flow when the MLSS reaches the clarifiers could denitrify, causing solids to rise to the surface and go over the weirs. To prevent solids from rising, the air is added to help maintain a D.O. of 0.5mg/L before traveling to the clarifiers.